A mimic of a (1!2),(1!6)-mannotrioside was synthesized by replacing the central mannose unit with an enantiomerically pure, conformationally stable trans-diaxial cyclohexanediol. The three-dimensional structure of the molecule was investigated by NMR spectroscopy supported by molecular modelling and was compared to the known features of the natural mannotrioside
Synthesis and Conformational Analysis of a α-Man-(1→2)-α-Man-(1→6)-α-Man Mimic / S. Mari, I. Sánchez-Medina, P. Mereghetti, L. Belvisi, J. Jiménez-Barbero, A. Bernardi. - In: CARBOHYDRATE RESEARCH. - ISSN 0008-6215. - 342:12/13(2007), pp. 1859-1868.
Synthesis and Conformational Analysis of a α-Man-(1→2)-α-Man-(1→6)-α-Man Mimic
S. MariPrimo
;P. Mereghetti;L. Belvisi;A. BernardiUltimo
2007
Abstract
A mimic of a (1!2),(1!6)-mannotrioside was synthesized by replacing the central mannose unit with an enantiomerically pure, conformationally stable trans-diaxial cyclohexanediol. The three-dimensional structure of the molecule was investigated by NMR spectroscopy supported by molecular modelling and was compared to the known features of the natural mannotrioside
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