Stereoselectivities of up to 98% have been found in the enzymic synthesis of b-hydroxy sulfoxides catalyzed by cyclohexanone monooxygenase (CHMO). The diastereoselectivity of the "one-pot" prepn. of the title compds. in the presence of bovine serum albumin has also been investigated.
Diastereoselective synthesis of beta-hydroxy sulfoxides: enzymatic and biomimetic approaches / S. Colonna, V. Pironti, F. Zambianchi, G. Ottolina, N. Gaggero, G. Celentano. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 2007:2(2007), pp. 363-368. [10.1002/ejoc.200600624]
Diastereoselective synthesis of beta-hydroxy sulfoxides: enzymatic and biomimetic approaches
S. Colonna
;V. PirontiSecondo
;N. GaggeroPenultimo
;G. CelentanoUltimo
2007
Abstract
Stereoselectivities of up to 98% have been found in the enzymic synthesis of b-hydroxy sulfoxides catalyzed by cyclohexanone monooxygenase (CHMO). The diastereoselectivity of the "one-pot" prepn. of the title compds. in the presence of bovine serum albumin has also been investigated.
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