One-dimensional metal-organic compounds with cis, trans symmetry-controlled counter anions were synthesized (cis compound {[Cu(azpy)(H2O)(2)(OTs)(2)]center dot 2H(2)O center dot(acetone)} (1) and trans compound {[Cu(H2O)(4)Cu(azpy)(2)(OTs)(2)(H2O)(2)]center dot 2(OTs)center dot 2H(2)O center dot 2EtOH} (2)). Only 2, having trans conformation, exhibited a complete structure-restoration effect with a mechanism involving layering of molecular "bricks" of water and solvent molecules.
Coordination symmetry-dependent structure restoration function of one-dimensional MOFs by molecular respiration / A. Kondo, H. Noguchi, H. Kajiro, L. Carlucci, P. Mercandelli, D.M. Proserpio, H. Tanaka, K. Kaneko, H. Kanoh. - In: JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL. - ISSN 1520-6106. - 110:51(2006), pp. 25565-25567. [10.1021/jp065438l]
Coordination symmetry-dependent structure restoration function of one-dimensional MOFs by molecular respiration
L. CarlucciSecondo
;P. Mercandelli;D.M. Proserpio;
2006
Abstract
One-dimensional metal-organic compounds with cis, trans symmetry-controlled counter anions were synthesized (cis compound {[Cu(azpy)(H2O)(2)(OTs)(2)]center dot 2H(2)O center dot(acetone)} (1) and trans compound {[Cu(H2O)(4)Cu(azpy)(2)(OTs)(2)(H2O)(2)]center dot 2(OTs)center dot 2H(2)O center dot 2EtOH} (2)). Only 2, having trans conformation, exhibited a complete structure-restoration effect with a mechanism involving layering of molecular "bricks" of water and solvent molecules.
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