• Several enantiopure 1,2-amino alcs. have been prepd. by combining a stereoselective enzymic epoxidn. of styrenes with regio- and stereoselective chem. reactions. An interesting reactivity has been noted concerning the ring opening of epoxides with NH3 under microwave activation.
Synthesis of enantiopure 2-amino-1-phenyl and 2-amino-2-phenyl ethanols using enantioselective enzymatic epoxidation and regio- and diastereoselective chemical aminolysis / Guido Sello, Fulvia Orsini, Silvana Bernasconi, Patrizia Di Gennaro. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - 17:3(2006), pp. 372-376. [10.1016/j.tetasy.2006.01.009]
Synthesis of enantiopure 2-amino-1-phenyl and 2-amino-2-phenyl ethanols using enantioselective enzymatic epoxidation and regio- and diastereoselective chemical aminolysis
Guido Sello;Fulvia Orsini;Silvana Bernasconi;
2006
Abstract
• Several enantiopure 1,2-amino alcs. have been prepd. by combining a stereoselective enzymic epoxidn. of styrenes with regio- and stereoselective chem. reactions. An interesting reactivity has been noted concerning the ring opening of epoxides with NH3 under microwave activation.
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