The synthesis of two new thiocyanate free Ru(ii) complexes with different pyrid-2-yl tetrazolate ligands is reported, along with their electrochemical, spectroscopic and theoretical characterization. The corresponding dye-sensitized solar cell devices were prepared, leading to 3.4% conversion efficiency, promising data, considering the simplicity of the ligands and the high chemical stability of the complexes.
New thiocyanate-free ruthenium(ii) sensitizers with different pyrid-2-yl tetrazolate ligands for dye-sensitized solar cells / A. Colombo, C. Dragonetti, M. Magni, D. Meroni, R. Ugo, G. Marotta, M.G. Lobello, P. Salvatori, F. De Angelis. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - 44:26(2015 May 15), pp. 11788-11796.
New thiocyanate-free ruthenium(ii) sensitizers with different pyrid-2-yl tetrazolate ligands for dye-sensitized solar cells
A. Colombo;C. Dragonetti;M. Magni;D. Meroni;R. Ugo;
2015
Abstract
The synthesis of two new thiocyanate free Ru(ii) complexes with different pyrid-2-yl tetrazolate ligands is reported, along with their electrochemical, spectroscopic and theoretical characterization. The corresponding dye-sensitized solar cell devices were prepared, leading to 3.4% conversion efficiency, promising data, considering the simplicity of the ligands and the high chemical stability of the complexes.
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