The four-coordinate complexes [PdBr(p-NCC6H4)(MeO-Biphep)], 1 [MeO-Biphep = 6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl], and [PdBr(p-NCC6H4)(p-tol-Binap)], 2 [p-tol-Binap = 2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl], both distort markedly, with the former no longer square-planar, and the latter, possessing the longest recorded Pd-P bond length.
Structural distortions in Pd-MeO-Biphep and Pd-Binap aryl complexes : anomalies induced via electronic effects / D. Drago, P. Pregosin, M. Tschoerner, A. Albinati. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - :14(1999), pp. 2279-2280.
Structural distortions in Pd-MeO-Biphep and Pd-Binap aryl complexes : anomalies induced via electronic effects
A. AlbinatiUltimo
1999
Abstract
The four-coordinate complexes [PdBr(p-NCC6H4)(MeO-Biphep)], 1 [MeO-Biphep = 6,6'-dimethoxy-2,2'-bis(diphenylphosphino)-1,1'-biphenyl], and [PdBr(p-NCC6H4)(p-tol-Binap)], 2 [p-tol-Binap = 2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl], both distort markedly, with the former no longer square-planar, and the latter, possessing the longest recorded Pd-P bond length.
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