The reactions of [Fe4C(CO)12(CuNCMe)x]x - 2(x = 1, 2) with ImiPr·HBF4(ImiPr = N,N′-bis(isopropyl)imidazol-2-ylidene) in the presence of NaH yielded [Fe4C(CO)12(CuImiPr)x]x - 2. The hetero-substituted [Fe4C(CO)12(CuCl)(CuImiPr)]-was obtained by the deprotonation of the corresponding chloride salt. All products have been characterized by elemental analysis, NMR and single crystal X-ray diffraction analyses.
N-heterocyclic carbene copper complexes tethered to iron carbidocarbonyl clusters / R. Della Pergola, A. Sironi, A. Rosehr, V. Colombo, A. Sironi. - In: INORGANIC CHEMISTRY COMMUNICATIONS. - ISSN 1387-7003. - 49(2014), pp. 27-29.
N-heterocyclic carbene copper complexes tethered to iron carbidocarbonyl clusters
A. SironiSecondo
;V. ColomboPenultimo
;A. SironiUltimo
2014
Abstract
The reactions of [Fe4C(CO)12(CuNCMe)x]x - 2(x = 1, 2) with ImiPr·HBF4(ImiPr = N,N′-bis(isopropyl)imidazol-2-ylidene) in the presence of NaH yielded [Fe4C(CO)12(CuImiPr)x]x - 2. The hetero-substituted [Fe4C(CO)12(CuCl)(CuImiPr)]-was obtained by the deprotonation of the corresponding chloride salt. All products have been characterized by elemental analysis, NMR and single crystal X-ray diffraction analyses.
| File | Dimensione | Formato | |
|---|---|---|---|
|
1-s2.0-S1387700314003906-main.pdf
accesso riservato
Tipologia:
Publisher's version/PDF
Dimensione
466.77 kB
Formato
Adobe PDF
|
466.77 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
Pubblicazioni consigliate
I metadati presenti in AIR sono rilasciati con licenza CCO mentre i file delle pubblicazioni sono rilasciati con licenza CC BY-SA, salvo diversa indicazione. In caso di violazione di copyright, contattare l'assistenza di AIR
