The reactions of [Fe4C(CO)12(CuNCMe)x]x - 2(x = 1, 2) with ImiPr·HBF4(ImiPr = N,N′-bis(isopropyl)imidazol-2-ylidene) in the presence of NaH yielded [Fe4C(CO)12(CuImiPr)x]x - 2. The hetero-substituted [Fe4C(CO)12(CuCl)(CuImiPr)]-was obtained by the deprotonation of the corresponding chloride salt. All products have been characterized by elemental analysis, NMR and single crystal X-ray diffraction analyses.

N-heterocyclic carbene copper complexes tethered to iron carbidocarbonyl clusters / R. Della Pergola, A. Sironi, A. Rosehr, V. Colombo, A. Sironi. - In: INORGANIC CHEMISTRY COMMUNICATIONS. - ISSN 1387-7003. - 49(2014), pp. 27-29.

N-heterocyclic carbene copper complexes tethered to iron carbidocarbonyl clusters

A. Sironi;V. Colombo;A. Sironi
2014

Abstract

The reactions of [Fe4C(CO)12(CuNCMe)x]x - 2(x = 1, 2) with ImiPr·HBF4(ImiPr = N,N′-bis(isopropyl)imidazol-2-ylidene) in the presence of NaH yielded [Fe4C(CO)12(CuImiPr)x]x - 2. The hetero-substituted [Fe4C(CO)12(CuCl)(CuImiPr)]-was obtained by the deprotonation of the corresponding chloride salt. All products have been characterized by elemental analysis, NMR and single crystal X-ray diffraction analyses.
Copper; Crystal structure; Heterometallic clusters; Interstitial carbide; Iron; NHC ligands
Settore CHIM/03 - Chimica Generale e Inorganica
INORGANIC CHEMISTRY COMMUNICATIONS
Article (author)
File in questo prodotto:
File Dimensione Formato  
1-s2.0-S1387700314003906-main.pdf

non disponibili

Tipologia: Publisher's version/PDF
Dimensione 466.77 kB
Formato Adobe PDF
466.77 kB Adobe PDF   Visualizza/Apri   Richiedi una copia
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/259587
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 9
  • ???jsp.display-item.citation.isi??? 8
social impact