Photocatalysis on TiO2, with irradiation wavelength 254 nm or 315- 400 nm, and sonolysis at 20 kHz were employed, either separately or simultaneously, or in the presence of hydrogen peroxide, as advanced oxidation techniques in the degradation of methyl tert-butyl ether (MTBE) in water under atmospheric conditions. MTBE generally underwent degradation according to a first-order rate law. The prevailing reaction paths were identified by monitoring the time profile of the main reaction intermediates (acetone, tert-butyl formate and tert-butyl alcohol). Hydroxyl radicals, able to attack both MTBE and its degradation intermediates, played a central role in all degradation conditions. The highest degradation and mineralization efficiency, in terms of both treatment duration and energy consumption, was achieved under hydrogen peroxide photolysis at 254 nm.
Kinetic analysis on the combined use of photocatalysis, H2O2 photolysis and sonolysis in the degradation of methyl tert-butyl ether / M. Bertelli, E. Selli. - In: APPLIED CATALYSIS. B, ENVIRONMENTAL. - ISSN 0926-3373. - 52:3(2004), pp. 205-212.
Kinetic analysis on the combined use of photocatalysis, H2O2 photolysis and sonolysis in the degradation of methyl tert-butyl ether
M. BertelliPrimo
;E. SelliUltimo
2004
Abstract
Photocatalysis on TiO2, with irradiation wavelength 254 nm or 315- 400 nm, and sonolysis at 20 kHz were employed, either separately or simultaneously, or in the presence of hydrogen peroxide, as advanced oxidation techniques in the degradation of methyl tert-butyl ether (MTBE) in water under atmospheric conditions. MTBE generally underwent degradation according to a first-order rate law. The prevailing reaction paths were identified by monitoring the time profile of the main reaction intermediates (acetone, tert-butyl formate and tert-butyl alcohol). Hydroxyl radicals, able to attack both MTBE and its degradation intermediates, played a central role in all degradation conditions. The highest degradation and mineralization efficiency, in terms of both treatment duration and energy consumption, was achieved under hydrogen peroxide photolysis at 254 nm.Pubblicazioni consigliate
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