The unexpected and acido-triggered reversible luminescence and nonlinear optical properties of (2-pyrene-1-yl-vinyl)pyridine, a simple and highly transparent chromophore, are studied both in solution and in the solid state. Remarkably, for the first time the acidomodulation of the NLO response of a poled thin film is reported.

Solid state and solution fine tuning of the linear and nonlinear optical properties of (2-pyrene-1-yl-vinyl)pyridine by protonation–deprotonation reactions / E. Cariati, C. Botta, S..G. Danelli, A. Forni, A. Giaretta, U. Giovanella, E. Lucenti, D. Marinotto, S. Righetto, R. Ugo. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 50:91(2014), pp. 14225-14228. [10.1039/c4cc05891g]

Solid state and solution fine tuning of the linear and nonlinear optical properties of (2-pyrene-1-yl-vinyl)pyridine by protonation–deprotonation reactions

E. Cariati
Primo
;
E. Lucenti;D. Marinotto;S. Righetto
Penultimo
;
R. Ugo
Ultimo
2014

Abstract

The unexpected and acido-triggered reversible luminescence and nonlinear optical properties of (2-pyrene-1-yl-vinyl)pyridine, a simple and highly transparent chromophore, are studied both in solution and in the solid state. Remarkably, for the first time the acidomodulation of the NLO response of a poled thin film is reported.
2ND-harmonic generation; polymer-films; molecular switches; efish measurements; poling dynamics; NLO-phores; thin-films; complexes; design; hyperpolarizabilities
Settore CHIM/03 - Chimica Generale e Inorganica
2014
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/249470
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