This feature article provides an overview of the application of organic azides for the intermolecular amination of sp(3) and sp(2) C-H bonds. The catalytic activity of several metal complexes was reviewed underlining both synthetic and mechanistic aspects of the C-H amination. The majority of the aminated compounds reported in literature have been collected in this paper to provide a compendium of published procedures. In addition, the discussion of involved mechanisms has been included to assist the reader to envisage the future potential of organic azides in the synthesis of aza-derivatives.
Organic azides : energetic reagents for the intermolecular amination of C-H bonds / D. Intrieri, P. Zardi, A. Caselli, E. Gallo. - In: CHEMICAL COMMUNICATIONS. - ISSN 1364-548X. - 50:78(2014 Oct 09), pp. 11440-11453. [10.1039/c4cc03016h]
Organic azides : energetic reagents for the intermolecular amination of C-H bonds
D. IntrieriPrimo
;P. ZardiSecondo
;A. CaselliPenultimo
;E. Gallo
2014
Abstract
This feature article provides an overview of the application of organic azides for the intermolecular amination of sp(3) and sp(2) C-H bonds. The catalytic activity of several metal complexes was reviewed underlining both synthetic and mechanistic aspects of the C-H amination. The majority of the aminated compounds reported in literature have been collected in this paper to provide a compendium of published procedures. In addition, the discussion of involved mechanisms has been included to assist the reader to envisage the future potential of organic azides in the synthesis of aza-derivatives.File | Dimensione | Formato | |
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