Mechanistic studies revealed ruthenium-catalyzed direct arylations to proceed through reversible C-H bond activation and subsequent rate-limiting oxidative addition with aryl halides, which led to the development of widely applicable well-defined ruthenium(II) carboxylate catalysts.
Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts / L. Ackermann, R. Vicente, H.K. Potukuchi, V. Pirovano. - In: ORGANIC LETTERS. - ISSN 1523-7060. - 12:21(2010 Nov 05), pp. 5032-5035.
Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts
V. Pirovano
2010
Abstract
Mechanistic studies revealed ruthenium-catalyzed direct arylations to proceed through reversible C-H bond activation and subsequent rate-limiting oxidative addition with aryl halides, which led to the development of widely applicable well-defined ruthenium(II) carboxylate catalysts.
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