Mechanistic studies revealed ruthenium-catalyzed direct arylations to proceed through reversible C-H bond activation and subsequent rate-limiting oxidative addition with aryl halides, which led to the development of widely applicable well-defined ruthenium(II) carboxylate catalysts.

Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts / L. Ackermann, R. Vicente, H.K. Potukuchi, V. Pirovano. - In: ORGANIC LETTERS. - ISSN 1523-7060. - 12:21(2010 Nov 05), pp. 5032-5035.

Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts

V. Pirovano
2010

Abstract

Mechanistic studies revealed ruthenium-catalyzed direct arylations to proceed through reversible C-H bond activation and subsequent rate-limiting oxidative addition with aryl halides, which led to the development of widely applicable well-defined ruthenium(II) carboxylate catalysts.
H BOND ACTIVATION ; C-H ; ARYL CHLORIDES ; COMPLEXES ; METAL ; FUNCTIONALIZATION ; CLEAVAGE ; BROMIDES ; ARENES ; ELECTROPHILES
Settore CHIM/06 - Chimica Organica
5-nov-2010
Article (author)
File in questo prodotto:
File Dimensione Formato  
pubbl.Organic letters.pdf

accesso aperto

Tipologia: Post-print, accepted manuscript ecc. (versione accettata dall'editore)
Dimensione 747.7 kB
Formato Adobe PDF
747.7 kB Adobe PDF Visualizza/Apri
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/234841
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 241
  • ???jsp.display-item.citation.isi??? 231
social impact