A series of ternary hydrotalcites in the nitrate form was prepared with a modified-urea method to obtain active Co-based catalysts for the Fischer–Tropsch synthesis. An optimization study concerning the amount of cobalt in the catalysts (range 5–35 wt%.) and the reaction temperature (220–260 C) is reported. All the samples were characterized by several methods, including XRPD, ICP-OES, SEM, TEM, FT-IR, BET, TPR and TG and tested in a fixed bed reactor. The results suggest the possibility of using synthetic hydrotalcites as Co-based catalysts for the Fischer–Tropsch synthesis.
Co-based hydrotalcites as new catalysts for the Fischer–Tropsch synthesis process / A. Di Fronzo, C. Pirola, A. Comazzi, F. Galli, C.L. Bianchi, A. Di Michele, R. Vivani, M. Nocchetti, M. Bastianini, D.C. Boffito. - In: FUEL. - ISSN 0016-2361. - 119(2014 Mar), pp. 62-69.
|Titolo:||Co-based hydrotalcites as new catalysts for the Fischer–Tropsch synthesis process|
|Parole Chiave:||Hydrotalcite ; Urea method ; Fischer–Tropsch Synthesis ; Cobalt-based catalysts|
|Settore Scientifico Disciplinare:||Settore CHIM/04 - Chimica Industriale|
|Data di pubblicazione:||mar-2014|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1016/j.fuel.2013.11.014|
|Appare nelle tipologie:||01 - Articolo su periodico|