Two highly porous coordination polymers, containing rare octanuclear hydroxo-nickel clusters and long bis-pyrazolyl spacers, are shown to possess, after mild thermal treatment, lattice cavities up to 72% of the total crystal volume.
Cubic Octanuclear Ni(II) Clusters in Highly Porous Polypyrazolyl-Based Materials / N. Masciocchi, S. Galli, V. Colombo, A. Maspero, G. Palmisano, B. Seyyedi, C. Lamberti, S. Bordiga. - In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. - ISSN 0002-7863. - 132:23(2010), pp. 7902-7904. [10.1021/ja102862j]
Cubic Octanuclear Ni(II) Clusters in Highly Porous Polypyrazolyl-Based Materials
V. Colombo;
2010
Abstract
Two highly porous coordination polymers, containing rare octanuclear hydroxo-nickel clusters and long bis-pyrazolyl spacers, are shown to possess, after mild thermal treatment, lattice cavities up to 72% of the total crystal volume.
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