Temperature matters! The separation efficiency of complex mixtures of gases (acetylene, carbon dioxide, methane, nitrogen) and vapors (benzene, cyclohex-ane) by adsorption on A[Cu3(μ3-OH) (μ3-4-carboxypyrazolato)3] (A@1) metal-organic frameworks depends on temperature and the extraframework cation A (see picture). NH4@1 also behaves as an oxidation catalyst.

Cation-Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis / E. Quartapelle Procopio, F. Linares, C. Montoro, V. Colombo, A. Maspero, E. Barea, J.A.R. Navarro. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 49:40(2010 Sep 24), pp. 7308-7311.

Cation-Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis

E. Quartapelle Procopio
Primo
;
V. Colombo;
2010

Abstract

Temperature matters! The separation efficiency of complex mixtures of gases (acetylene, carbon dioxide, methane, nitrogen) and vapors (benzene, cyclohex-ane) by adsorption on A[Cu3(μ3-OH) (μ3-4-carboxypyrazolato)3] (A@1) metal-organic frameworks depends on temperature and the extraframework cation A (see picture). NH4@1 also behaves as an oxidation catalyst.
gas separation ; heterogeneous catalysis ; ion exchange ; microporous materials ; porous coordination polymers
Settore CHIM/03 - Chimica Generale e Inorganica
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/223211
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