Temperature matters! The separation efficiency of complex mixtures of gases (acetylene, carbon dioxide, methane, nitrogen) and vapors (benzene, cyclohex-ane) by adsorption on A[Cu3(μ3-OH) (μ3-4-carboxypyrazolato)3] (A@1) metal-organic frameworks depends on temperature and the extraframework cation A (see picture). NH4@1 also behaves as an oxidation catalyst.
Cation-Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis / E. Quartapelle Procopio, F. Linares, C. Montoro, V. Colombo, A. Maspero, E. Barea, J.A.R. Navarro. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 49:40(2010 Sep 24), pp. 7308-7311.
Cation-Exchange Porosity Tuning in Anionic Metal–Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis
E. Quartapelle ProcopioPrimo
;V. Colombo;
2010
Abstract
Temperature matters! The separation efficiency of complex mixtures of gases (acetylene, carbon dioxide, methane, nitrogen) and vapors (benzene, cyclohex-ane) by adsorption on A[Cu3(μ3-OH) (μ3-4-carboxypyrazolato)3] (A@1) metal-organic frameworks depends on temperature and the extraframework cation A (see picture). NH4@1 also behaves as an oxidation catalyst.File | Dimensione | Formato | |
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