The bidentate ferrocenyl sandwich [Fe(η5-C5H4-1- C5H4N)2] (1) has been used as a coordination ligand in reactions with AgNO3, Cd(NO3)2, Cu(CH3COO)2, Zn(CH3COO)2, and ZnCl2 to obtain the heterobimetallic metallamacrocyclic derivatives [Fe(η5-C5H4-1- C5H4N)2]2Ag2 (NO3)2·1.5H2O, [Fe(η5-C5H4-1- C5H4N)2]2 Cu2(CH3COO)4·3H2O, [Fe(η5-C5H4-1-C5H4N) 2]2-Cd2 (NO3)4·CH3OH·0.5C6 H6, [Fe(η5-C5H4-1- C5H4N)2]2Zn2 (CH3COO)4, and [Fe(η5- C5H4-1-C5H4N) 2]2Zn2Cl4 (abbreviated in the following as (1AgI)22+, (1CdII)24+, (1CuII)24+, (1ZnIIacetate)24+, and (1ZnIIchloride)24+). The reaction with the ferrocenedicarboxylic acid complex [Fe(η5- C5H4COOH)2] has led to the supramolecular adduct [Fe(η5-C5H4-1- C5H4N)2][Fe(η5- C5H4COOH) 2](1[Fe(η5- C5H4COOH)2]). All compounds have been structurally characterized by single-crystal X-ray diffraction.

Design, Synthesis, and Structural Characterization of Molecular and Supramolecular Heterobimetallic Metallamacrocycles Based on the 1,1‘-Bis(4-pyridyl)ferrocene (Fe(η5-C5H4-1-C5H4N)2) Ligand / D. Braga, M. Polito, D. D'Addario, E. Tagliavini, D.M. Proserpio, F. Grepioni, J.W. Steed. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 22:22(2003), pp. 4532-4538.

Design, Synthesis, and Structural Characterization of Molecular and Supramolecular Heterobimetallic Metallamacrocycles Based on the 1,1‘-Bis(4-pyridyl)ferrocene (Fe(η5-C5H4-1-C5H4N)2) Ligand

D.M. Proserpio;
2003

Abstract

The bidentate ferrocenyl sandwich [Fe(η5-C5H4-1- C5H4N)2] (1) has been used as a coordination ligand in reactions with AgNO3, Cd(NO3)2, Cu(CH3COO)2, Zn(CH3COO)2, and ZnCl2 to obtain the heterobimetallic metallamacrocyclic derivatives [Fe(η5-C5H4-1- C5H4N)2]2Ag2 (NO3)2·1.5H2O, [Fe(η5-C5H4-1- C5H4N)2]2 Cu2(CH3COO)4·3H2O, [Fe(η5-C5H4-1-C5H4N) 2]2-Cd2 (NO3)4·CH3OH·0.5C6 H6, [Fe(η5-C5H4-1- C5H4N)2]2Zn2 (CH3COO)4, and [Fe(η5- C5H4-1-C5H4N) 2]2Zn2Cl4 (abbreviated in the following as (1AgI)22+, (1CdII)24+, (1CuII)24+, (1ZnIIacetate)24+, and (1ZnIIchloride)24+). The reaction with the ferrocenedicarboxylic acid complex [Fe(η5- C5H4COOH)2] has led to the supramolecular adduct [Fe(η5-C5H4-1- C5H4N)2][Fe(η5- C5H4COOH) 2](1[Fe(η5- C5H4COOH)2]). All compounds have been structurally characterized by single-crystal X-ray diffraction.
Settore CHIM/03 - Chimica Generale e Inorganica
2003
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/207693
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