Low temperature synthesis has produced a new selenoantimonate, [Fe(en) 3][enH]SbSe 4 (I). Crystals of I were grown at 160°C in ethylenediamine solution. Compound I crystallizes in triclinic crystal system, space group P-1 (no. 2), with unit cell constants a = 8.916(2) Å, b = 9.679(2) Å, c = 14.345(4) Å, α = 104.71(3)°, β = 92.51(2)°, γ = 110.14(2)°, V = 1112.4(5) Å 3 and Z = 2. Structural refinement using 2850 reflections (F o > 4((F o)] and 204 variables resulted in 0.04 for R1 and 0.06 for wR2. I contains molecular Zintl anions (SbSe 4) 3- and metal coordination complex [Fe(en) 3] 2+ and [enH] + cations. The metal complex is present with 72% as lel 2ob conformer and 28% as lel 3 conformer.
Preparation and crystal structure of a selenoantimonate [Fe(en)3][enH]SbSe4 / M.R. Girard, J. Li, D.Μ. Proserpio. - In: MAIN GROUP METAL CHEMISTRY. - ISSN 0792-1241. - 21:4(1998), pp. 231-236. [10.1515/MGMC.1998.21.4.231]
Preparation and crystal structure of a selenoantimonate [Fe(en)3][enH]SbSe4
D.Μ. ProserpioUltimo
1998
Abstract
Low temperature synthesis has produced a new selenoantimonate, [Fe(en) 3][enH]SbSe 4 (I). Crystals of I were grown at 160°C in ethylenediamine solution. Compound I crystallizes in triclinic crystal system, space group P-1 (no. 2), with unit cell constants a = 8.916(2) Å, b = 9.679(2) Å, c = 14.345(4) Å, α = 104.71(3)°, β = 92.51(2)°, γ = 110.14(2)°, V = 1112.4(5) Å 3 and Z = 2. Structural refinement using 2850 reflections (F o > 4((F o)] and 204 variables resulted in 0.04 for R1 and 0.06 for wR2. I contains molecular Zintl anions (SbSe 4) 3- and metal coordination complex [Fe(en) 3] 2+ and [enH] + cations. The metal complex is present with 72% as lel 2ob conformer and 28% as lel 3 conformer.Pubblicazioni consigliate
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