A novel synthetic strategy based on the intramolecular palladium-catalyzed oxidative cyclization reaction, allows the formation of C-C bond and the synthesis of β-carbolinones. The reaction has been performed in the presence of catalytic amount of PdCl2(CH3CN)2 and benzoquinone as a reoxidant.
Uncommon intramolecular palladium-catalyzed cyclization of indole derivatives / E.M. Beccalli, G. Broggini. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 44:9(2003), pp. 1919-1921.
Uncommon intramolecular palladium-catalyzed cyclization of indole derivatives
E.M. BeccalliPrimo
;
2003
Abstract
A novel synthetic strategy based on the intramolecular palladium-catalyzed oxidative cyclization reaction, allows the formation of C-C bond and the synthesis of β-carbolinones. The reaction has been performed in the presence of catalytic amount of PdCl2(CH3CN)2 and benzoquinone as a reoxidant.
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