The adducts A.ZaBr2, B.2nBr2, A.CdI2, A.CdBr2, C.CdI2, B.CdI2, C.HgCI2, C.2HgCl2, D.HgCI2, A.Rh(CO)2Cl were prepared from the corresponding halide and the ligand A, (Ph3P)(ArNC)Pt-[c(OMe)=NAr]2 B, (DFE)Pt{c(OMe)=NAr]2, C, (DPE)Pt-[c(OMe)=NMe]2or D, (DPE)Pt-|c(OMe)=NCgH112(Ar= p-tolyl, DPE= 1,2-bis(diphenylphosphino) ethane). These platinum(II) bidentate ligands are basic since they can be proton at ed at the two imino nitrogens, which are likely to be the donor sites in the adducts.
An Investigation on Various Bis (N-substituted-imino)(alkoxy)methyl platinum(II) Derivatives as Ligands Towards Group IIB Halides and Rhodium Dicarbonyl Chloride / G. Banditelli, A.L. Bandini, G. Minghetti, F. Bonati. - In: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY. - ISSN 0094-5714. - 9:6(1979), pp. 539-555.
An Investigation on Various Bis (N-substituted-imino)(alkoxy)methyl platinum(II) Derivatives as Ligands Towards Group IIB Halides and Rhodium Dicarbonyl Chloride
G. BanditelliPrimo
;A.L. BandiniSecondo
;
1979
Abstract
The adducts A.ZaBr2, B.2nBr2, A.CdI2, A.CdBr2, C.CdI2, B.CdI2, C.HgCI2, C.2HgCl2, D.HgCI2, A.Rh(CO)2Cl were prepared from the corresponding halide and the ligand A, (Ph3P)(ArNC)Pt-[c(OMe)=NAr]2 B, (DFE)Pt{c(OMe)=NAr]2, C, (DPE)Pt-[c(OMe)=NMe]2or D, (DPE)Pt-|c(OMe)=NCgH112(Ar= p-tolyl, DPE= 1,2-bis(diphenylphosphino) ethane). These platinum(II) bidentate ligands are basic since they can be proton at ed at the two imino nitrogens, which are likely to be the donor sites in the adducts.
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