Alkylcerium reagents add to the multiple bonds of allyl and propargyl alcohols in good yields and under mild conditions. The double bond can be reduced with lithium aluminum hydride in the presence of cerium trichloride. The regiochemistry of the attack depends on electronic factors.
Allyl Alcohols and Organocerium Reagents, II Mechanism and Extensibility of the Reaction / G. Bartoli, M. C. Bellucci, M. Bosco, R. Dalpozzo, A. De Nino, L. Sambri, A. Tagarelli. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 2000:1(2000), pp. 99-104. [10.1002/(SICI)1099-0690(200001)2000:1<99::AID-EJOC99>3.0.CO;2-1]
Allyl Alcohols and Organocerium Reagents, II Mechanism and Extensibility of the Reaction
M.C. BellucciSecondo
;
2000
Abstract
Alkylcerium reagents add to the multiple bonds of allyl and propargyl alcohols in good yields and under mild conditions. The double bond can be reduced with lithium aluminum hydride in the presence of cerium trichloride. The regiochemistry of the attack depends on electronic factors.
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