Alkylcerium reagents add to the multiple bonds of allyl and propargyl alcohols in good yields and under mild conditions. The double bond can be reduced with lithium aluminum hydride in the presence of cerium trichloride. The regiochemistry of the attack depends on electronic factors.

Allyl Alcohols and Organocerium Reagents, II Mechanism and Extensibility of the Reaction / G. Bartoli, M. C. Bellucci, M. Bosco, R. Dalpozzo, A. De Nino, L. Sambri, A. Tagarelli. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - 2000:1(2000), pp. 99-104. [10.1002/(SICI)1099-0690(200001)2000:1<99::AID-EJOC99>3.0.CO;2-1]

Allyl Alcohols and Organocerium Reagents, II Mechanism and Extensibility of the Reaction

M.C. Bellucci
Secondo
;
2000

Abstract

Alkylcerium reagents add to the multiple bonds of allyl and propargyl alcohols in good yields and under mild conditions. The double bond can be reduced with lithium aluminum hydride in the presence of cerium trichloride. The regiochemistry of the attack depends on electronic factors.
Addition reactions; Alkenes; Allyl alcohols; Cerium; Organocerium reagents
Settore CHIM/06 - Chimica Organica
Article (author)
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/198752
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