The first compound in which a hydride- and an alkylidene-ligand bridge two Pt-atoms is present in the complex cation 2, which is formed on reaction of the complex 1 with styrene. 2 was characterized NMR spectroscopically and by an X-ray structure analysis. the Pt[BOND]Pt distance of 2.735(1) Å indicates that there is bonding interaction between the two metal atoms.
SYNTHESIS AND STRUCTURE OF [PT2(MU-H)(MU-CHCH2PH)(DIPHOS)2][BF4] / G. MINGHETTI, A. ALBINATI, A. BANDINI, G. BANDITELLI. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH. - ISSN 0570-0833. - 24:2(1985), pp. 120-121.
SYNTHESIS AND STRUCTURE OF [PT2(MU-H)(MU-CHCH2PH)(DIPHOS)2][BF4]
A. ALBINATI;A. BANDINI;G. BANDITELLI
1985
Abstract
The first compound in which a hydride- and an alkylidene-ligand bridge two Pt-atoms is present in the complex cation 2, which is formed on reaction of the complex 1 with styrene. 2 was characterized NMR spectroscopically and by an X-ray structure analysis. the Pt[BOND]Pt distance of 2.735(1) Å indicates that there is bonding interaction between the two metal atoms.
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