Reaction of [Ru3(CO)12] with [Mn(CO) 5]- gives [Ru6(CO)18]2- which on acidification is converted into [HRu6(CO)18] -; this monoanion has spectroscopic properties and an X-ray structure consistent with the H ligand lying at the centre of an octahedron (approximating to Oh symmetry) of ruthenium atoms.
[HRu6(CO)18]- : a ruthenium anion having an interstitial H-ligand: X-ray crystal structures of two modifications / C.R. Eady, B.F.G. Jonhson, J. Lewis, M.C. Malatesta, P. Machin, M. Mcpartland. - In: CHEMICAL COMMUNICATIONS. - ISSN 0366-5607. - 22(1976), pp. 945-946. [10.1039/C39760000945]
[HRu6(CO)18]- : a ruthenium anion having an interstitial H-ligand: X-ray crystal structures of two modifications
M.C. Malatesta;
1976
Abstract
Reaction of [Ru3(CO)12] with [Mn(CO) 5]- gives [Ru6(CO)18]2- which on acidification is converted into [HRu6(CO)18] -; this monoanion has spectroscopic properties and an X-ray structure consistent with the H ligand lying at the centre of an octahedron (approximating to Oh symmetry) of ruthenium atoms.
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