FAB mass spectrometric measurements on several Au(I) derivatives of 1,4-benzodiazepin-2-ones provided information about the stability of these compounds. For all the complexes containing the moiety Au(PPh3), the base peak is the ionic species [Au(PPh3)]+. Otherwise, the positive charge is localized in the benzodiazepinic ligand.
FAB MASS-SPECTROMETRY OF AU(I) COMPLEXES WITH 1,4-BENZODIAZEPIN-2-ONES / G. BANDITELLI, A. BANDINI, M. CINELLU, G. MINGHETTI, M. SCANDOLA, P. TRALDI. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 183:1(1991), pp. 51-56.
FAB MASS-SPECTROMETRY OF AU(I) COMPLEXES WITH 1,4-BENZODIAZEPIN-2-ONES
G. BANDITELLIPrimo
;A. BANDINISecondo
;
1991
Abstract
FAB mass spectrometric measurements on several Au(I) derivatives of 1,4-benzodiazepin-2-ones provided information about the stability of these compounds. For all the complexes containing the moiety Au(PPh3), the base peak is the ionic species [Au(PPh3)]+. Otherwise, the positive charge is localized in the benzodiazepinic ligand.File in questo prodotto:
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