Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··)4 (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers.
The Two-Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of[Mn(3-MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6] / H. Miyasaka, N. Matsumoto, H. Ōkawa, N. Re, E. Gallo, C. Floriani. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION IN ENGLISH. - ISSN 0570-0833. - 34:13-14(1995), pp. 1446-1448. [10.1002/anie.199514461]
The Two-Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of[Mn(3-MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6]
E. GalloPenultimo
;
1995
Abstract
Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··)4 (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers.
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