The oxidation of primary aromatic amines to the corresponding nitro derivatives has been observed in catalytic systems (turnovers/hour up to 18000) containing tert-butyl hydroperoxide and metallo-tetraaryl porphyrins (metal = FeIII or MnIII) in the presence of heterocyclic nitrogen bases acting as axial ligands.
Oxidation of primary aromatic amines to nitro derivatives catalyzed by iron(III) and manganese(III) tetraaryl porphyrins / S. Tollari, D. Vergani, S. Banfi, F. Porta. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :5(1993), pp. 442-444.
Oxidation of primary aromatic amines to nitro derivatives catalyzed by iron(III) and manganese(III) tetraaryl porphyrins
F. Porta
1993
Abstract
The oxidation of primary aromatic amines to the corresponding nitro derivatives has been observed in catalytic systems (turnovers/hour up to 18000) containing tert-butyl hydroperoxide and metallo-tetraaryl porphyrins (metal = FeIII or MnIII) in the presence of heterocyclic nitrogen bases acting as axial ligands.
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