A kinetic model is presented which considers the catalytic reduction of NO to N2 by hydrocarbons in oxidizing atmosphere (NO-HC-O2) as the sum of two simultaneous competitive reactions: the red-ox reaction between NO and hydrocarbon (NO-HC) and the hydrocarbon oxidation (O2-HC). The model is developed for alkenes employed as reductants and noble metal catalysts, The ratio of the kinetic constants of the two reactions can be considered as a selectivity index in evaluating the ability of a catalyst to favor the desired NO reduction with respect to the undesired O2-HC oxidation.
On the kinetics of catalytic reduction of nitrogen oxide by alkenes in oxidizing atmosphere / P. Carniti, A. Gervasini. - In: REACTION KINETICS AND CATALYSIS LETTERS. - ISSN 0133-1736. - 67:2(1999), pp. 233-239.
|Titolo:||On the kinetics of catalytic reduction of nitrogen oxide by alkenes in oxidizing atmosphere|
CARNITI, PAOLO (Primo)
GERVASINI, ANTONELLA (Ultimo)
|Settore Scientifico Disciplinare:||Settore CHIM/02 - Chimica Fisica|
|Data di pubblicazione:||1999|
|Digital Object Identifier (DOI):||http://dx.doi.org/10.1007/BF02475765|
|Appare nelle tipologie:||01 - Articolo su periodico|