The trinuclear complex [Cu3PHI]6+, derived from a ligand containing two chiral L-histidine residues, performs the catalytic oxidation of L- and D-Dopa with remarkable enantio-differentiation; this depends on the anchoring effect provided by the copper center which is not participating in the catalytic reaction and recognizes the chirality of the substrate.

Enantio-differentiating catalytic oxidation by a biomimetic trinuclear copper complex containing L-histidine residues / L. Santagostini, M. Gullotti, R. Pagliarin, E. Monzanic, L. Casella. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 9:17(2003), pp. 2186-2187.

Enantio-differentiating catalytic oxidation by a biomimetic trinuclear copper complex containing L-histidine residues

L. Santagostini;R. Pagliarin;
2003

Abstract

The trinuclear complex [Cu3PHI]6+, derived from a ligand containing two chiral L-histidine residues, performs the catalytic oxidation of L- and D-Dopa with remarkable enantio-differentiation; this depends on the anchoring effect provided by the copper center which is not participating in the catalytic reaction and recognizes the chirality of the substrate.
Settore CHIM/06 - Chimica Organica
CHEMICAL COMMUNICATIONS
Article (author)
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate

Caricamento pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/194302
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 32
  • ???jsp.display-item.citation.isi??? 25
social impact