The trinuclear complex [Cu3PHI]6+, derived from a ligand containing two chiral L-histidine residues, performs the catalytic oxidation of L- and D-Dopa with remarkable enantio-differentiation; this depends on the anchoring effect provided by the copper center which is not participating in the catalytic reaction and recognizes the chirality of the substrate.
Enantio-differentiating catalytic oxidation by a biomimetic trinuclear copper complex containing L-histidine residues / L. Santagostini, M. Gullotti, R. Pagliarin, E. Monzanic, L. Casella. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 9:17(2003), pp. 2186-2187.
Titolo: | Enantio-differentiating catalytic oxidation by a biomimetic trinuclear copper complex containing L-histidine residues |
Autori: | SANTAGOSTINI, LAURA (Primo) |
Settore Scientifico Disciplinare: | Settore CHIM/06 - Chimica Organica |
Data di pubblicazione: | 2003 |
Rivista: | |
Tipologia: | Article (author) |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/b307349a |
Appare nelle tipologie: | 01 - Articolo su periodico |