The trinuclear complex [Cu3PHI]6+, derived from a ligand containing two chiral L-histidine residues, performs the catalytic oxidation of L- and D-Dopa with remarkable enantio-differentiation; this depends on the anchoring effect provided by the copper center which is not participating in the catalytic reaction and recognizes the chirality of the substrate.
Enantio-differentiating catalytic oxidation by a biomimetic trinuclear copper complex containing L-histidine residues / L. Santagostini, M. Gullotti, R. Pagliarin, E. Monzanic, L. Casella. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 9:17(2003), pp. 2186-2187.
Enantio-differentiating catalytic oxidation by a biomimetic trinuclear copper complex containing L-histidine residues
L. Santagostini;R. Pagliarin;
2003
Abstract
The trinuclear complex [Cu3PHI]6+, derived from a ligand containing two chiral L-histidine residues, performs the catalytic oxidation of L- and D-Dopa with remarkable enantio-differentiation; this depends on the anchoring effect provided by the copper center which is not participating in the catalytic reaction and recognizes the chirality of the substrate.
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