1,2-Diaroyldiaziridines react with octacarbonyldicobalt in benzene, at 65-70°C, to give dihydro-oxazoles by an intramolecular displacement- rearrangement reaction; thermal rearrangement of the strained-ring heterocycles affords 4,5-dihydro-oxadiazoles.
OCTACARBONYLDICOBALT INDUCED CONVERSION OF 1,2-DIAROYLDIAZIRIDINES INTO DIHYDRO-OXAZOLES (OXAZOLINES) / D. ROBERTO, H. ALPER. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :3(1987), pp. 212-213. [10.1039/c39870000212]
OCTACARBONYLDICOBALT INDUCED CONVERSION OF 1,2-DIAROYLDIAZIRIDINES INTO DIHYDRO-OXAZOLES (OXAZOLINES)
D. RobertoPrimo
;
1987
Abstract
1,2-Diaroyldiaziridines react with octacarbonyldicobalt in benzene, at 65-70°C, to give dihydro-oxazoles by an intramolecular displacement- rearrangement reaction; thermal rearrangement of the strained-ring heterocycles affords 4,5-dihydro-oxadiazoles.
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