In the presence of samarium iodide alpha-halophosphonates react with aliphatic carbonyl compounds (aldehydes and ketones) to afford beta-hydroxyphosphonates in fairly good yields under neutral and mild conditions. Lower yields are obtained with aromatic carbonyl compounds.
A new entry to β-hydroxyphosphonates: the SmI2-mediated reaction of diethyl iodomethylphosphonate with carbonyl compounds / F. Orsini, A. Caselli. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 43:40(2002 Sep 30), pp. 7255-7257.
A new entry to β-hydroxyphosphonates: the SmI2-mediated reaction of diethyl iodomethylphosphonate with carbonyl compounds
F. Orsini;A. Caselli
2002
Abstract
In the presence of samarium iodide alpha-halophosphonates react with aliphatic carbonyl compounds (aldehydes and ketones) to afford beta-hydroxyphosphonates in fairly good yields under neutral and mild conditions. Lower yields are obtained with aromatic carbonyl compounds.
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