Attempts to convert saturated (5α- and 5β-) 19-hydroxylated steroids to 19-halogenated analogues with the use of mixed phosphorus and halogen containing reagents are described. The 19-halogenated analogues were not obtained, but certain transformations in the 5α series and rearrangements in the 5β series were noted and are discussed.
Reaction of saturated (5α- and 5β-) 19-hydroxy steroids with mixed phosphorus and halogen containing reagents / E. Santaniello, E. Caspi, W.L.Duax,C.M. Weeks,. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 42:3(1977), pp. 482-486. [10.1021/jo00423a019]
Reaction of saturated (5α- and 5β-) 19-hydroxy steroids with mixed phosphorus and halogen containing reagents
E. SantanielloPrimo
;
1977
Abstract
Attempts to convert saturated (5α- and 5β-) 19-hydroxylated steroids to 19-halogenated analogues with the use of mixed phosphorus and halogen containing reagents are described. The 19-halogenated analogues were not obtained, but certain transformations in the 5α series and rearrangements in the 5β series were noted and are discussed.File in questo prodotto:
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