A new free-radical azocoupling has been accomplished by decomposition of diazonium salts with monoelectronic reducing agents in the presence of 4-methyl-3-penten-2-one. Steric and polar factors are responsible of the unusual behaviour.
Steric and polar effects in free-radical reactions. - An unusual type of azocoupling by free radical decomposition of diazonium salts / A. Citterio, F. Minisci, A. Albinati, S. Bruckner. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 21:30(1980), pp. 2909-2910.
Steric and polar effects in free-radical reactions. - An unusual type of azocoupling by free radical decomposition of diazonium salts
A. AlbinatiPenultimo
;
1980
Abstract
A new free-radical azocoupling has been accomplished by decomposition of diazonium salts with monoelectronic reducing agents in the presence of 4-methyl-3-penten-2-one. Steric and polar factors are responsible of the unusual behaviour.
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