N-Phenylsulfonyl unsaturated imines (1) react with 2,4-diphenyl-3-methyl-1,3-oxazolium 5-oxide (2) giving 4-styrylimidazoles (3), open chain products (4) and pyrrol-3-ylcarboxaldehyde N-phenylsulfonylimines (5). The mechanism of formation of all the products as well as the different behaviour of imines 1 compared with those lacking the N-tosyl group are discussed. The structures have been assigned on the basis of 1H NMR evidence and by X-ray analysis.
|Titolo:||Cycloaddition reactions of N-phenylsulfonyl-1-azabuta-1,3-dienes with mesoionic 2,4-diphenyl-1-methyl-1,3-oxazolium 5-oxide|
DALLA CROCE, PIERO (Primo)
LA ROSA, CONCETTA (Penultimo)
|Settore Scientifico Disciplinare:||Settore CHIM/06 - Chimica Organica|
|Data di pubblicazione:||1993|
|Appare nelle tipologie:||01 - Articolo su periodico|