The tetrakis(trimethylphosphine)cobalt(0) complex, [Co{P(CH3)3}4], in either stoichiometric or catalytic amounts, was shown to be an efficient mediator for a one-pot Reformatsky-type reaction between activated halogen derivatives (esters, amides, lactones) and carbonyl compounds (aldehydes, ketones) to produce a variety of alcohols.
A COBALT-PHOSPHINE COMPLEX AS MEDIATOR IN THE FORMATION OF CARBON-CARBON BONDS / F. ORSINI, F. PELIZZONI, M. PULICI, L. VALLARINO. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - 59:1(1994), pp. 1-3.
A COBALT-PHOSPHINE COMPLEX AS MEDIATOR IN THE FORMATION OF CARBON-CARBON BONDS
F. ORSINI;F. PELIZZONI;
1994
Abstract
The tetrakis(trimethylphosphine)cobalt(0) complex, [Co{P(CH3)3}4], in either stoichiometric or catalytic amounts, was shown to be an efficient mediator for a one-pot Reformatsky-type reaction between activated halogen derivatives (esters, amides, lactones) and carbonyl compounds (aldehydes, ketones) to produce a variety of alcohols.
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