A new entry to the drimane-related sesquiterpene Confertifolin is reported. The key step involves the conversion of a β-phenylthio-α,β-unsaturated ketone into the corresponding silylcyanohydrin followed by diisobutylaluminum hydride reduction to the homologous α,β-unsaturated aldehyde.
Diisobutylaluminum Hydride Reduction of Unsaturated Sylylcyanohydrins: A New Entry to Confertifolin / G. Jommi, R. Pagliarin, M. Sisti, P. Tavecchia. - In: SYNTHETIC COMMUNICATIONS. - ISSN 0039-7911. - 19:13-14(1989), pp. 2467-2480. [10.1080/00397918908052649]
Diisobutylaluminum Hydride Reduction of Unsaturated Sylylcyanohydrins: A New Entry to Confertifolin
R. PagliarinSecondo
;
1989
Abstract
A new entry to the drimane-related sesquiterpene Confertifolin is reported. The key step involves the conversion of a β-phenylthio-α,β-unsaturated ketone into the corresponding silylcyanohydrin followed by diisobutylaluminum hydride reduction to the homologous α,β-unsaturated aldehyde.
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