Sterically protected tri- and hexanuclear platinum clusters were used as building blocks for the high-yield synthesis of a first-generation dendrimer (see picture; tBu groups are omitted for clarity), which is chemically and thermally stable, and in which the cluster units are separated by conjugated 1,3,5-triethynylphenyl groups.
Assembling metal clusters with covalent linkers: Synthesis and structure of a quasi-planar Pt-18 dendrimer containing five clusters connected by sigma-alkynyl spacers / A. Albinati, P. Leoni, L. Marchetti, S. Rizzato. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 42:48(2003), pp. 5990-5993.
Titolo: | Assembling metal clusters with covalent linkers: Synthesis and structure of a quasi-planar Pt-18 dendrimer containing five clusters connected by sigma-alkynyl spacers | |
Autori: | ALBINATI, ALBERTO (Primo) RIZZATO, SILVIA (Ultimo) | |
Parole Chiave: | Alkyne ligands; Cluster compounds; Dendrimers; Metal-metal interactions; Platinum | |
Settore Scientifico Disciplinare: | Settore CHIM/03 - Chimica Generale e Inorganica | |
Data di pubblicazione: | 2003 | |
Rivista: | ||
Tipologia: | Article (author) | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/anie.200352954 | |
Appare nelle tipologie: | 01 - Articolo su periodico |