The reactions of 2-(tosylamino)benzyltrimethylammonium halides (1) with dimethylsulfonium 2-oxo-2-phenylethylide (6b), dimethylsulfonium 2-ethoxy-2-oxo-ethylide (6c) and dimethylsulfonium cyanomethylide (6d) are useful synthetic routes to 2-substituted indoles (8b-d). The relationship between reaction conditions and selectivity is discussed.

2-(Tosylamino)benzyltrimethylammonium halides as precursors of 2-substituted indoles / P. Dalla Croce, R. Ferraccioli, C. La Rosa. - In: HETEROCYCLES. - ISSN 0385-5414. - 43:11(1996), pp. 2397-2407.

2-(Tosylamino)benzyltrimethylammonium halides as precursors of 2-substituted indoles

P. Dalla Croce
Primo
;
C. La Rosa
Ultimo
1996

Abstract

The reactions of 2-(tosylamino)benzyltrimethylammonium halides (1) with dimethylsulfonium 2-oxo-2-phenylethylide (6b), dimethylsulfonium 2-ethoxy-2-oxo-ethylide (6c) and dimethylsulfonium cyanomethylide (6d) are useful synthetic routes to 2-substituted indoles (8b-d). The relationship between reaction conditions and selectivity is discussed.
Settore CHIM/06 - Chimica Organica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/191191
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