The preparation and X-ray crystal structure of the monohydrido-bridged cation [(η5-C5H5) 2(H)W(μ-H)Pt-(Ph)(PEt3)2]+ and of the dihydrido-bridged cation [(η5-C5H5)2W(μ-H) 2Pt(Ph)(PEt3)]+ are reported. Structural and NMR data show that the W-Pt interaction is considerably stronger in the dihydrido than in the related monohydrido-bridged species.
Mono- and dihydrido-bridged tungsten-platinum complexes / A. Albinati, R. Naegeli, A. Togni, L. M. Venanzi. - In: ORGANOMETALLICS. - ISSN 0276-7333. - 2:7(1983), pp. 926-928.
Mono- and dihydrido-bridged tungsten-platinum complexes
A. AlbinatiPrimo
;
1983
Abstract
The preparation and X-ray crystal structure of the monohydrido-bridged cation [(η5-C5H5) 2(H)W(μ-H)Pt-(Ph)(PEt3)2]+ and of the dihydrido-bridged cation [(η5-C5H5)2W(μ-H) 2Pt(Ph)(PEt3)]+ are reported. Structural and NMR data show that the W-Pt interaction is considerably stronger in the dihydrido than in the related monohydrido-bridged species.
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