The cation [(PPh3)(Ph)Pt(μ-H)(μ-PPh2)Pt(PPh3)2]+ (III), was obtained from the reaction of [Pt(1,5-C8H12)12)2], trans-[Pt(Ph)(acetone)(PPh3)2] [BF4], PPh3 and H2. The molecular structure of III is reported. It is shown that the Ph and Ph2P fragments arise from the cleavage of one molecule of PPh3.
Some new monohydridomonophosphido bridged diplatinum complexes / J. Jans, R. Naegeli, L. M. Venanzi, A. Albinati. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 247:2(1983), pp. c37-c41. [10.1016/S0022-328X(00)98766-7]
Some new monohydridomonophosphido bridged diplatinum complexes
A. AlbinatiUltimo
1983
Abstract
The cation [(PPh3)(Ph)Pt(μ-H)(μ-PPh2)Pt(PPh3)2]+ (III), was obtained from the reaction of [Pt(1,5-C8H12)12)2], trans-[Pt(Ph)(acetone)(PPh3)2] [BF4], PPh3 and H2. The molecular structure of III is reported. It is shown that the Ph and Ph2P fragments arise from the cleavage of one molecule of PPh3.
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