The cation [(PPh3)(Ph)Pt(μ-H)(μ-PPh2)Pt(PPh3)2]+ (III), was obtained from the reaction of [Pt(1,5-C8H12)12)2], trans-[Pt(Ph)(acetone)(PPh3)2] [BF4], PPh3 and H2. The molecular structure of III is reported. It is shown that the Ph and Ph2P fragments arise from the cleavage of one molecule of PPh3.

Some new monohydridomonophosphido bridged diplatinum complexes / J. Jans, R. Naegeli, L. M. Venanzi, A. Albinati. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 247:2(1983), pp. c37-c41.

Some new monohydridomonophosphido bridged diplatinum complexes

A. Albinati
Ultimo
1983

Abstract

The cation [(PPh3)(Ph)Pt(μ-H)(μ-PPh2)Pt(PPh3)2]+ (III), was obtained from the reaction of [Pt(1,5-C8H12)12)2], trans-[Pt(Ph)(acetone)(PPh3)2] [BF4], PPh3 and H2. The molecular structure of III is reported. It is shown that the Ph and Ph2P fragments arise from the cleavage of one molecule of PPh3.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/191109
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