The structure of di-1,5-cyclooctadienesilver tetrafluoroborate was determined from single crystal X-ray diffraction data. The silver atom is four coordinated to the olefinic ends of the two cyclooctadiene molecules in a modified tetrahedral coordination described as "cubical". Bond lengths and other structural parameters are discussed and compared with the corresponding data found for other d10 and d8 olefin-metal complexes.

The crystal structure of the olefin complex di-1,5-cyclooctadienesilver tetrafluoroborate / A. Albinati, S. Meille, G. Carturan. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 182:2(1979), pp. 269-274.

The crystal structure of the olefin complex di-1,5-cyclooctadienesilver tetrafluoroborate

A. Albinati
Primo
;
1979

Abstract

The structure of di-1,5-cyclooctadienesilver tetrafluoroborate was determined from single crystal X-ray diffraction data. The silver atom is four coordinated to the olefinic ends of the two cyclooctadiene molecules in a modified tetrahedral coordination described as "cubical". Bond lengths and other structural parameters are discussed and compared with the corresponding data found for other d10 and d8 olefin-metal complexes.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/190931
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