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EnglishIn the reported experiment, photochemically induced grafting (1) and graft polymerization (2) from N,N-dimethylformamide solutions of four acryloxy-substituted aromatic diazenes, chosen as model molecules of acryloxy azo dyes, were investigated kinetically at 25 degree C onto polypropylene, polycaprolactam, and poly(ethylene terephthalate) films, by polychromatic irradiations. Quantum efficiencies at zero concentration of dyes and lifetimes of excited states for processes (1) and (2) were evaluated from experimental data by Stern-Volmer plots. The surface density of grafted molecules at the end of process (1) was not affected by the concentration of dyes in solution, but varied sensibly with the chemical nature of polymers and dyes. The relevant parameters are discused on the basis of the proposed mechanism.
PHOTOCHEMICAL GRAFTING OF ACRYLATED AZO DYES ONTO POLYMERIC SURFACES - 5. GRAFTING OF SOME ACRYLOXY-SUBSTITUTED AROMATIC DIAZENES AS MODEL MOLECULES ONTO POLYPROPYLENE, POLYCAPROLACTAM, AND POLY(ETHYLENE TEREPHTHALATE) FILMS / S. Calgari, E. Selli, I.R. Bellobono. - In: JOURNAL OF APPLIED POLYMER SCIENCE. - ISSN 0021-8995. - 27:2(1982), pp. 527-533.
| Titolo: | PHOTOCHEMICAL GRAFTING OF ACRYLATED AZO DYES ONTO POLYMERIC SURFACES - 5. GRAFTING OF SOME ACRYLOXY-SUBSTITUTED AROMATIC DIAZENES AS MODEL MOLECULES ONTO POLYPROPYLENE, POLYCAPROLACTAM, AND POLY(ETHYLENE TEREPHTHALATE) FILMS |
| Autori: | SELLI, ELENA (Secondo) BELLOBONO, IGNAZIO RENATO (Ultimo) |
| Parole Chiave: | reaction kinetics ; plastics films ; polyamides ; polyesters ; polypropylene ; photochemical reactions ; grafting mechanisms ; polycaprolactam ; dyes and dyeing |
| Settore Scientifico Disciplinare: | Settore CHIM/02 - Chimica Fisica Settore CHIM/04 - Chimica Industriale |
| Data di pubblicazione: | 1982 |
| Rivista: | |
| Tipologia: | Article (author) |
| Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/app.1982.070270216 |
| Appare nelle tipologie: | 01 - Articolo su periodico |
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