The e.s.r. spectra in dimethoxyethane and tetrahydrofuran of the ion pairs formed by 4-nitropyridine anion radical with lithium, sodium and potassium cations have been studied at various temperatures. The temperature dependence of the alkali metal splitting is interpreted on the basis of the Atherton-Weissman model. To discuss the structure of the ion pair, different quantum mechanical calculations were performed.
Ion Pairs formed by Alkali Metals / P.Cremaschi, A.Gamba, G.Morosi, C.Oliva, M.Simonetta. - In: JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS II. - ISSN 0300-9238. - 71(1975), pp. 1829-1838.
Ion Pairs formed by Alkali Metals
C.OlivaPenultimo
;
1975
Abstract
The e.s.r. spectra in dimethoxyethane and tetrahydrofuran of the ion pairs formed by 4-nitropyridine anion radical with lithium, sodium and potassium cations have been studied at various temperatures. The temperature dependence of the alkali metal splitting is interpreted on the basis of the Atherton-Weissman model. To discuss the structure of the ion pair, different quantum mechanical calculations were performed.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
