The internal rotation in the free anion radicals and the ion pairs from 3-nitroacetophenone and 4-nitroacetophenone is studied on the basis of their dynamic EPR spectra in solution. Energy barriers and related thermodynamic parameters which govern internal rotation and rotational diffusion of the studied systems have been provided together with a discussion about the accuracy and the reliability of their determination.

Analysis of Restricted Rotation of the Acetyl Group in m- and p- Nitroacetophenone Anion Radicals / M.Branca, A.Gamba, C.Oliva, M.Simonetta. - In: CHEMICAL PHYSICS. - ISSN 0301-0104. - 75:2(1983), pp. 253-262. [10.1016/0301-0104(83)85024-1]

Analysis of Restricted Rotation of the Acetyl Group in m- and p- Nitroacetophenone Anion Radicals

C. Oliva
Penultimo
;
1983

Abstract

The internal rotation in the free anion radicals and the ion pairs from 3-nitroacetophenone and 4-nitroacetophenone is studied on the basis of their dynamic EPR spectra in solution. Energy barriers and related thermodynamic parameters which govern internal rotation and rotational diffusion of the studied systems have been provided together with a discussion about the accuracy and the reliability of their determination.
Settore CHIM/02 - Chimica Fisica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/189544
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