The reaction of [Pt(CO)Cl(ROOCCC(Cl)COOR)] and of the anions [cisPt(CO)Cl2(ROOCCC(Cl)COOR)]- (R = Me or Et) with primary and secondary alcohols (MeOH, EtOH, n-PrOH, i-PrOH, allyl-OH) gives rise to specific alcoholysis of the γ-alkoxy group. The specificity is interpreted in terms of the interaction of the β-carboalkoxy group with platinum. The crystal structure of (PPN)[cis-Pt(CO)Cl2(EtOOCCC(Cl)COOPr-i)] has been solved by X-ray analysis.

Reactions of acetylenes with noble-metal carbonyl halides .3. chemical and structural studies of sigma-alkenyl complexes of platinum(II) / F. Canziani, A. Albinati, L. Garlaschelli, M. Malatesta. - In: JOURNAL OF ORGANOMETALLIC CHEMISTRY. - ISSN 0022-328X. - 146:2(1978), pp. 197-211.

Reactions of acetylenes with noble-metal carbonyl halides .3. chemical and structural studies of sigma-alkenyl complexes of platinum(II)

A. Albinati
Secondo
;
1978

Abstract

The reaction of [Pt(CO)Cl(ROOCCC(Cl)COOR)] and of the anions [cisPt(CO)Cl2(ROOCCC(Cl)COOR)]- (R = Me or Et) with primary and secondary alcohols (MeOH, EtOH, n-PrOH, i-PrOH, allyl-OH) gives rise to specific alcoholysis of the γ-alkoxy group. The specificity is interpreted in terms of the interaction of the β-carboalkoxy group with platinum. The crystal structure of (PPN)[cis-Pt(CO)Cl2(EtOOCCC(Cl)COOPr-i)] has been solved by X-ray analysis.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/189277
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