Carbon disulphide inserts into the PtH bond of trans-{PtH2[P(C6H11)3]2} to give trans-{PtH(S2CH) [P(C6H11)3]2}. The X-ray structure shows that the -S2CH group is bonded to the metal through a sulfur atom as a monodentate thioformate anion. The kinetics of the carbon disulfide insertion have been investigated. The results account for a mechanism involving CS2 addition to trans-{PtH2[P(C6H113]2} to give a five-coordinate intermediate, which collapses to trans-{PtH(S2CH)[P(C6H11)3]2}.

Reaction of trans-{PtH2[P(C6H11)3]2} with carbon disulphide. Kinetic study of the insertion reaction and X-ray structure of trans-{PtH(S2CH)[P(C6H11)3]2} / A. Albinati, A. Musco, G. Carturan, G. Strukul. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 18:C(1976), pp. 219-223. [10.1016/S0020-1693(00)95607-X]

Reaction of trans-{PtH2[P(C6H11)3]2} with carbon disulphide. Kinetic study of the insertion reaction and X-ray structure of trans-{PtH(S2CH)[P(C6H11)3]2}

A. Albinati
Primo
;
1976

Abstract

Carbon disulphide inserts into the PtH bond of trans-{PtH2[P(C6H11)3]2} to give trans-{PtH(S2CH) [P(C6H11)3]2}. The X-ray structure shows that the -S2CH group is bonded to the metal through a sulfur atom as a monodentate thioformate anion. The kinetics of the carbon disulfide insertion have been investigated. The results account for a mechanism involving CS2 addition to trans-{PtH2[P(C6H113]2} to give a five-coordinate intermediate, which collapses to trans-{PtH(S2CH)[P(C6H11)3]2}.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/189248
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