The hydroformylation of 1-octene catalysed by the title compounds has been examined at 135 °C under an atmosphere of H2 and CO at a pressure of 85 atm. The influence on the activity and selectivity of various parameters such as the nature of the metal, the nuclearity of the original complex and the electronic and steric effects induced by the substituents on the cyclopentadienyl ligand has been investigated and discussed.
Homogeneous catalysis by transition metal complexes. Part VI. Hydroformylation of 1-octene catalyzed by [h5- C5R5M(CO)2X] and [h5-C5R5M(CO)2]2 species (R = hydrogen, methyl, or phenyl; M = iron or ruthenium; X = chlorine, bromine, or iodine) / E. Cesarotti, R. Ugo, A. Fusi. - In: JOURNAL OF MOLECULAR CATALYSIS. - ISSN 0304-5102. - 10:2(1981), pp. 213-221.
Homogeneous catalysis by transition metal complexes. Part VI. Hydroformylation of 1-octene catalyzed by [h5- C5R5M(CO)2X] and [h5-C5R5M(CO)2]2 species (R = hydrogen, methyl, or phenyl; M = iron or ruthenium; X = chlorine, bromine, or iodine)
E. CesarottiPrimo
;
1981
Abstract
The hydroformylation of 1-octene catalysed by the title compounds has been examined at 135 °C under an atmosphere of H2 and CO at a pressure of 85 atm. The influence on the activity and selectivity of various parameters such as the nature of the metal, the nuclearity of the original complex and the electronic and steric effects induced by the substituents on the cyclopentadienyl ligand has been investigated and discussed.
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