The intermediacy of CO/NO substitution in the condensation of [Pt19(CO)22]4- into [Pt38(CO)44]2- (structure shown) has been demonstrated. Two high-nuclearity carbonyl metal clusters, including one with an unprecedented nitrosyl ligand, have been synthesized and structurally characterized.
[Pt-19(CO)(21)(NO)](3-) and [Pt-38(CO)(44)](2-): Nitrosyl bending through intramolecular electron transfer as an intermediate step in the nucleation process from polydecker to ccp platinum carbonyl clusters / A. Ceriotti, N. Masciocchi, P. Macchi, G. Longoni. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - 38:24(1999), pp. 3724-3727.
[Pt-19(CO)(21)(NO)](3-) and [Pt-38(CO)(44)](2-): Nitrosyl bending through intramolecular electron transfer as an intermediate step in the nucleation process from polydecker to ccp platinum carbonyl clusters
A. CeriottiPrimo
;
1999
Abstract
The intermediacy of CO/NO substitution in the condensation of [Pt19(CO)22]4- into [Pt38(CO)44]2- (structure shown) has been demonstrated. Two high-nuclearity carbonyl metal clusters, including one with an unprecedented nitrosyl ligand, have been synthesized and structurally characterized.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
