Reaction of K[(η3-C7H7)Fe(CO) 3] with [(1,5-η4-C8H12) Pd(η5-C5H5)]BF4 gives the title compound which is the first case of a bridging cycloheptatrienyl metal-metal bonded complex having an uncoordinated double bond in the ring and detectable low-temperature limiting 1H and 13C NMR spectra.
Synthesis, fluxional behaviour and X-ray crystal structure of [Fe(CO) 3(μ-η3:η2-C7H 7)Pd(η5-C5H5)] / M. Airoldi, G. Deganello, G. Gennaro, M. Moret, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :11(1992), pp. 850-851.
Synthesis, fluxional behaviour and X-ray crystal structure of [Fe(CO) 3(μ-η3:η2-C7H 7)Pd(η5-C5H5)]
A. SironiUltimo
1992
Abstract
Reaction of K[(η3-C7H7)Fe(CO) 3] with [(1,5-η4-C8H12) Pd(η5-C5H5)]BF4 gives the title compound which is the first case of a bridging cycloheptatrienyl metal-metal bonded complex having an uncoordinated double bond in the ring and detectable low-temperature limiting 1H and 13C NMR spectra.
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