New tertiary amino polymers having the structure of poly(esterthioetheramine)s have been prepared by polyaddition of 2,2'-alkylenediiminodiethanethiols to bisacrylic esters and bismethacrylic esters. Kinetic measurements performed on polymerization rate show that the latter are less reactive towards polyaddition reaction. Moreover the presence of protogenic substances in the reaction medium considerably enhances the polyaddition rate.

NEW BASIC MULTIFUNCTIONAL POLYMERS .5. POLY(ESTERTHIOETHERAMINE)S BY POLYADDITION OF 2,2'-ALKYLENEDIIMINO DIETHANETHIOLS TO BISACRYLIC AND BISMETHACRYLIC ESTERS / E. RANUCCI, Ferruti, P.. - In: POLYMER. - ISSN 0032-3861. - 32:15(1991), pp. 2876-2879. [10.1016/0032-3861(91)90122-Y]

NEW BASIC MULTIFUNCTIONAL POLYMERS .5. POLY(ESTERTHIOETHERAMINE)S BY POLYADDITION OF 2,2'-ALKYLENEDIIMINO DIETHANETHIOLS TO BISACRYLIC AND BISMETHACRYLIC ESTERS

E. Ranucci
Primo
;
1991

Abstract

New tertiary amino polymers having the structure of poly(esterthioetheramine)s have been prepared by polyaddition of 2,2'-alkylenediiminodiethanethiols to bisacrylic esters and bismethacrylic esters. Kinetic measurements performed on polymerization rate show that the latter are less reactive towards polyaddition reaction. Moreover the presence of protogenic substances in the reaction medium considerably enhances the polyaddition rate.
Settore CHIM/04 - Chimica Industriale
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/188334
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