X-ray crystal structures, solid-state photoluminescence, and Kurtz-Perry powder second harmonic generation (SHG) efficiencies of two novel noncentrosymmetric polymeric adducts of CuI with 4-acetylpyridine, a double-stranded "stair" and a single-stranded "chain", are reported, the latter being a rare example of a [CuX(L)2]n motif (X = halide, L = pseudoaromatic η1-nitrogen donor ligand). In a series of structurally related noncentrosymmetric [CuX(L)]n chains and stairs, the powder SHG responses are interpreted in terms of both structural motifs (chains showing definitely greater efficiency than stairs) and "intrastrand" charge transfers involving the bridging halides.

X-ray structures and emissive and second-order nonlinear optical properties of two inorganic-organic polymeric adducts of CuI with 4-acetylpyridine. The role of both "intrastrand" charge transfers and structural motifs on the nonlinear optical response of Cu(I) polymeric adducts with pseudoaromatic η 1-nitrogen donor ligands / E. Cariati, D. Roberto, R. Ugo, P. C. Ford, S. Galli, A. Sironi. - In: CHEMISTRY OF MATERIALS. - ISSN 0897-4756. - 14:12(2002), pp. 5116-5123.

X-ray structures and emissive and second-order nonlinear optical properties of two inorganic-organic polymeric adducts of CuI with 4-acetylpyridine. The role of both "intrastrand" charge transfers and structural motifs on the nonlinear optical response of Cu(I) polymeric adducts with pseudoaromatic η 1-nitrogen donor ligands

E. Cariati
Primo
;
D. Roberto
Secondo
;
R. Ugo;A. Sironi
Ultimo
2002

Abstract

X-ray crystal structures, solid-state photoluminescence, and Kurtz-Perry powder second harmonic generation (SHG) efficiencies of two novel noncentrosymmetric polymeric adducts of CuI with 4-acetylpyridine, a double-stranded "stair" and a single-stranded "chain", are reported, the latter being a rare example of a [CuX(L)2]n motif (X = halide, L = pseudoaromatic η1-nitrogen donor ligand). In a series of structurally related noncentrosymmetric [CuX(L)]n chains and stairs, the powder SHG responses are interpreted in terms of both structural motifs (chains showing definitely greater efficiency than stairs) and "intrastrand" charge transfers involving the bridging halides.
Settore CHIM/03 - Chimica Generale e Inorganica
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2434/188249
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