The novel anion [Rh14N2(CO)25] 2-, obtained by pyrolysis of [Rh6N(CO)15] -, contains a metal-centred tetradecanuclear metallic polyhedron, with two interstitial nitrogen atoms, both five-connected to rhodium atoms.
A novel high-nuclearity rhodium carbonyl cluster compound containing two interstitial nitrogen atoms : Synthesis and X-ray structure of the anion [Rh 14N2(CO)25]2 / S. Martinengo, G. Ciani, A. Sironi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - 1(1991), pp. 26-27. [10.1039/C39910000026]
A novel high-nuclearity rhodium carbonyl cluster compound containing two interstitial nitrogen atoms : Synthesis and X-ray structure of the anion [Rh 14N2(CO)25]2
G. CianiSecondo
;A. SironiUltimo
1991
Abstract
The novel anion [Rh14N2(CO)25] 2-, obtained by pyrolysis of [Rh6N(CO)15] -, contains a metal-centred tetradecanuclear metallic polyhedron, with two interstitial nitrogen atoms, both five-connected to rhodium atoms.
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